E I DUPONT DE NEMOURS & CO INC -- KROVAR II DF HERBICIDE, M0000032  -- 6840-00N015283
<pre>=====================  Product Identification  =====================

Product ID:KROVAR II DF HERBICIDE, M0000032
MSDS Date:02/01/1988
FSC:6840
NIIN:00N015283
=== Responsible Party ===
Company Name:E I DUPONT DE NEMOURS & CO INC
Address:1007 MARKET STREET
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-441-7515
Emergency Phone Num:800-441-3637;800-424-9300(CHEMTREC)
CAGE:0ERJ7
=== Contractor Identification ===
Company Name:E I DUPONT DE NEMOURS & CO, INC.
Address:1007 MARKET STREET
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515
CAGE:0ERJ7
Company Name:E.I. DUPONT DE NEMOURS & CO
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515;800-441-9442
CAGE:18873

=============  Composition/Information on Ingredients  =============

Ingred Name:ING 13: CONDUCTED AT HASKELL LAB, BROMACIL HAS BEEN RPTD TO
    BE NON-MUTAGENIC IN 5 OF 6 PT/GENE MUTATION (SEE ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14: STUDIES, 6 OF 6 PRIMARY DNA DMG STUDIES & 3 OF 4
    TESTS FOR CHROMOSOMAL EFTS. DIURON: THE CMPD IS (SEE ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15: A SKIN IRRITANT, IS AN EYE IRRITANT, & IS NOT A
    SKIN SENSIT IN ANIMALS. TOXIC EFTS DESCRIBED IN (SEE ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16: ANIMALS FROM SHORT EXPOS BY INHAL, INGEST/SKIN CONT
    INCL: BLOOD EFTS, SPLEEN EFTS, THYROID EFTS, (SEE ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17: METHEMOGLOBINEMIA, & NONSPECIFIC EFTS SUCH AS
    WEIGHT LOSS & IRRIT. TESTS IN SOME ANIMALS INDICATE (SEE ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18: THAT THE CMPD MAY HAVE EMBRYOTOXIC ACTIVITY. ANIMAL
    TESTING INDICATES THAT THIS CMPD DOES NOT HAVE (SEE ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19: MUTAGENIC/REPRO EFTS. HUMAN HLTH EFTS OF OVEREXP BY
    INHAL, INGEST/SKIN/EYE CONT MAY INITIALLY INCL: (SEE ING 21)
RTECS #:9999999ZZ

Ingred Name:ING 20: SKIN IRRIT W/DISCOMFORT/RASH; EYE IRRIT
    W/DISCOMFORT, TEARING/BLURRING OF VISION; LIVER ENLARGEMENT;(SEE
    ING 22)
RTECS #:9999999ZZ

Ingred Name:ING 21: SPLEEN & THYROID EFTS; RED BLOOD CELL
    DESTRUCTION;/REDUCTION OF BLOOD'S OXYGEN CARRYING CAPACITY W/ (SEE
    ING 23)
RTECS #:9999999ZZ

Ingred Name:ING 22: CYANOSIS (BLUISH DISCOLORATION), WEAKNESS/SHORTNESS
    OF BREATH BY FORMATION OF METHEMOGLOBIN. (SEE ING 24)
RTECS #:9999999ZZ

Ingred Name:ING 23: SIGNIFICANT SKIN PERMEATION AFTER CONT APPEARS
    UNLIKELY. THERE ARE NOT RPTS OF HUMAN SENSIT.
RTECS #:9999999ZZ

Ingred Name:BROMACIL
CAS:314-40-9
RTECS #:YQ9100000
Fraction by Wt: 53%
OSHA PEL:1 PPM
ACGIH TLV:10 MG/M3; 9192

Ingred Name:DIURON  (SARA III)
CAS:330-54-1
RTECS #:YS8925000
Fraction by Wt: 27%
OSHA PEL:10 MG/M3
ACGIH TLV:10 MG/M3; 9192
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS

Ingred Name:INERT INGREDIENTS
Fraction by Wt: 20%

Ingred Name:HNDLG/STOR PREC: DO NOT STORE WITH OTHER PESTICIDES,
    FERTILIZER, FOOD OR FEED. SUPP DATA: STATISTICALLY (SEE ING 5)
RTECS #:9999999ZZ

Ingred Name:ING 4: SIGNIFICANT INCR IN TOTAL LIVER TUMORS WAS SEEN IN
    MALE MICE ONLY. NEITHER CARCINOMAS NOR ADENOMAS (SEE ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5: CONSIDERED SEPARATELY WERE STATISTICALLY
    SIGNIFICANT, NOR WERE USUAL TUMOR TYPES NOTED. STATISTICALLY (SEE
    ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6: SIGNIFICANT INCREASES IN NATURALLY OCCURING,
    NON-NEOPLASTIC TESTICULAR LESIONS WERE SEEN AT ALL (SEE ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: MALE TREATMENT LEVELS, AND IN LIVER LESIONS AT ALL
    MALE & ONLY THE HIGHEST FEMALE TREATMENT GROUPS. (SEE ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8: DOG FEEDING STUDY: IN A 24-MONTH STUDY 0, 50, 250,
    AND 1250 PPM, NO NUTRITIONAL, CLINICAL, (SEE ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9: HEMATOLOGICAL, URINARY, BIOCHEMICAL/PATHOLOGICAL
    EVIDENCE OF TOXICITY WAS OBSERVED IN ANY TEST GP. (SEE ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10: REPRO (RATS): DIETARY ADMIN OF 0 & 250 PPM BROMACIL
    DID NOT AFFECT NORMAL REPRO/LACTATION IN A (SEE ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11: 3-GENERATION, 6 LITTER REPRO STUDY.
    TERATONGENICITY: RBTS WERE FED 0, 50, & 250 PPM BROMACIL IN (SEE
    ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12: DIET. BROMACIL WAS NEITHER EMBRYOTOXIC NOR
    TERATOGENIC AT ANY LEVEL. MUTAGENICITY: IN STUDIES NOT (SEE ING 14)
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:SEE HEALTH HAZARDS
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:CAUTION! HARMFUL IF SWALLOWED. CAUSES
    MOD EYE INJURY. ACUTE ORAL (RTS): LD50 IS 2,300 MG/KG (MALE); 1,300
    MG/KG (FEMALES). SLIGHTLY TOXIC BY INGEST. ACUTE DERM (RBTS): LD50
    >2,000 MG/KG. SLIGHTLY TO M OD TOXIC BY CONT. NOT A PRIMARY SKIN
    IRRITANT. NOT A SKIN SENSITIZER. EYE: MOD IRRITANT. CORNEAL (SEE
    EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: OPACITY & OTHER EFTS PRESENT AT FOUR
    DAYS AFTER TREATMENT. ALL EFTS REVERSED WITHIN 7 DAYS. (CHRONIC)
    BROMACIL: RAT FEEDING STUDY: IN A 24-MONTH STUDY AT 0, 50, 250 &
    1250 PPM, NO CLINICAL,  HEMATOLOGICAL, URINARY, OR BIOCHEMICAL
    EVIDENCE OF TOXICITY WAS OBSERVED IN THE TEST GROUPS. AT HIGHEST
    (SEE SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP,
    PREF MOUTH-TO-MOUTH. IF BRTHG IS DFCLT, GIVE OXYGEN. CALL MD. SKIN:
    FLUSH W/WATER. EYE: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15
    MIN. CAL L MD. INGEST: INDUCE VOMIT IMMED BY GIVING TWO GLASSES OF
    WATER & STICKING FINGER DOWN THROAT. NEVER GIVE ANYTHING BY MOUTH
    TO UNCONS PERSON. CALL MD.

=====================  Fire Fighting Measures  =====================

Lower Limits:0.135 G/L
Extinguishing Media:WATER SPRAY, CHEMICAL FOAM, DRY CHEMICAL & CO*2.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
    PROTECTIVE EQUIPMENT . USE WATER SPRAY. COOL TANK/CONTAINER WITH
    WATER SPRAY.
Unusual Fire/Explosion Hazard:DUST FORMS EXPLO MIXT W/AIR. IF AREA IS
    HEAVILY EXPSD TO FIRE & IF CNDTNS PERMIT, LET FIRE BURN ITSELF OUT
    SINCE WATER MAY INCR CONTAMINATION HAZARD.

==================  Accidental Release Measures  ==================

Spill Release Procedures:REVIEW FIRE & EXPLO HAZ & SAFETY PREC BEFORE
    PROCEEDING W/CLEAN UP. USE APPROP PERSONAL PROT EQUIP DURING CLEAN
    UP. SHOVEL/SWEEP UP. IF SPILL AREA IS ON GROUND NEAR VALUABLE
    PLANTS/TREES, REMOVE TOP 2	INCHES OF SOIL AFTER INITIAL CLEANUP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE IN WELL VENT AREA. KEEP CNTNR
    TIGHTLY CLSD. DO NOT STORE/CONSUME FOOD, DRINK/TOBACCO IN AREAS
    WHERE THEY MAY BECOME CONTAM W/MATL. (SEE ING 4)
Other Precautions:AVOID BREATHING VAPORS OR MIST. AVOID BREATHING DUST.
    AVOID CONTACT WITH EYES, SKIN, OR CLOTHING. AVOID DUST GENERATION.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
    EXPOSURE OF CONCERN .
Ventilation:USE ONLY WITH ADEQUATE VENTILATION.
Protective Gloves:NONE SPECIFIED BY MANUFACTURER.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. WASH CLOTHING
    AFTER USE.
Supplemental Safety and Health
EFTS OF OVEREXP: LEVEL, SLIGHT BODY WEIGHT RETARDATION WAS SEEN IN
    FEMALES & THYROID EFTS WERE SEEN IN MALES & FEMALES. THE NO-EFT
    LEVEL WAS 250 PPM. NO ONCOGENIC EFTS WERE SEEN AT ANY LEVEL.
    (MICE):  IN AN 18-MONTH FEEDING STUDY, MICE WEREFED 0, 250, 1,250,
    OR 5,000 PPM BROMACIL. AT HIGHEST RATE, A (SEE ING 4)

==================  Physical/Chemical Properties  ==================

pH:7.4@2%
Solubility in Water:DISPERSIBLE
Appearance and Odor:SOLID IVORY WITH NO ODOR.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:DECOMPOSES WITH HEAT.

====================  Disposal Considerations  ====================

Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION AND DISPOSAL
    MUST BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE, AND LOCAL
    REGULATIONS.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.